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- W2902254243 abstract "A direct synthesis of 3-(bromomethylene)isobenzofuran-1(3H)-ones from 2-alkynylbenzoic acids is developed through a regioselective 5-exo-dig bromocyclization. The reaction proceeds smoothly with a broad substrate scope. The products can be further elaborated via a palladium-catalyze cross-coupling reaction, or can convert to other heterocycles through simple operation. Preliminary mechanistic studies reveal that this transformation undergoes a radical process." @default.
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- W2902254243 date "2019-03-01" @default.
- W2902254243 modified "2023-10-14" @default.
- W2902254243 title "Synthesis of 3-(Bromomethylene)isobenzofuran-1(3H)-ones through regioselective 5-exo-dig bromocyclization of 2-alkynylbenzoic acids" @default.
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- W2902254243 doi "https://doi.org/10.1016/j.tet.2018.11.045" @default.
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