Matches in SemOpenAlex for { <https://semopenalex.org/work/W2902278282> ?p ?o ?g. }
- W2902278282 endingPage "220" @default.
- W2902278282 startingPage "213" @default.
- W2902278282 abstract "Novel porous nitrogen-doped carbon supported Pd (Pd@N-C) catalytic composites were prepared by one-pot thermal carbonization of chitosan/poly(ethylene glycol)‑block‑poly(propylene glycol)‑block‑poly(ethylene glycol)/PdCl2 (CS/P123/PdCl2) blend hydrogel membranes at different temperature in N2 atmosphere. The porous structure of the Pd@N-C catalytic composite was governed by both the addition of P123 and the carbonization temperature. At highest carbonization temperature of 900 °C, the prepared Pd@N-C catalytic composite from CS/P123/PdCl2 blend membrane showed the highest specific area (SBET) of 293.7 m2/g and total volume of pores (Vtot) of 0.79 cm3/g. The chemical state of the elements of C, N, O, Pd within the Pd@N-C catalytic composites were confirmed with X-ray photoelectron spectroscopy (XPS) measurements. Raman spectrum results showed that the prepared Pd@N-C catalytic composite contained mainly disordered carbon together with some graphite carbon. Pd nanoparticles sized in 5-20 nm dispersed well on the porous matrix of the carbon. The Pd@N-C catalytic composites showed excellent activities for the Ullmann homo-coupling reactions of aromatic halides, and can be recycled for 10 times. In such one-pot carbonization process, the polymer porogen is simultaneously decomposed without further etching and removal steps, which simplifies the preparation process and is beneficial to obtain Pd@N-C catalytic composites with desirable Pd loading." @default.
- W2902278282 created "2018-12-11" @default.
- W2902278282 creator A5004093347 @default.
- W2902278282 creator A5017362236 @default.
- W2902278282 creator A5022950764 @default.
- W2902278282 creator A5024669485 @default.
- W2902278282 creator A5033697778 @default.
- W2902278282 creator A5047297176 @default.
- W2902278282 creator A5069633552 @default.
- W2902278282 date "2019-03-01" @default.
- W2902278282 modified "2023-10-15" @default.
- W2902278282 title "One-pot carbonization of chitosan/P123/PdCl2 blend hydrogel membranes to N-doped carbon supported Pd catalytic composites for Ullmann reactions" @default.
- W2902278282 cites W1221807499 @default.
- W2902278282 cites W151268127 @default.
- W2902278282 cites W1828740639 @default.
- W2902278282 cites W1839852133 @default.
- W2902278282 cites W1965417239 @default.
- W2902278282 cites W1971356157 @default.
- W2902278282 cites W1975814449 @default.
- W2902278282 cites W1978614335 @default.
- W2902278282 cites W1982632848 @default.
- W2902278282 cites W1984026613 @default.
- W2902278282 cites W1989248335 @default.
- W2902278282 cites W2009425724 @default.
- W2902278282 cites W2010129710 @default.
- W2902278282 cites W2011388674 @default.
- W2902278282 cites W2016187188 @default.
- W2902278282 cites W2022335943 @default.
- W2902278282 cites W2030223910 @default.
- W2902278282 cites W2044421721 @default.
- W2902278282 cites W2060912642 @default.
- W2902278282 cites W2061119072 @default.
- W2902278282 cites W2063194409 @default.
- W2902278282 cites W2067478939 @default.
- W2902278282 cites W2070691884 @default.
- W2902278282 cites W2073540615 @default.
- W2902278282 cites W2078771835 @default.
- W2902278282 cites W2082556769 @default.
- W2902278282 cites W2083462236 @default.
- W2902278282 cites W2085130601 @default.
- W2902278282 cites W2086549485 @default.
- W2902278282 cites W2087005224 @default.
- W2902278282 cites W2090563446 @default.
- W2902278282 cites W2114717580 @default.
- W2902278282 cites W2119849616 @default.
- W2902278282 cites W2138177542 @default.
- W2902278282 cites W2188944707 @default.
- W2902278282 cites W2346493207 @default.
- W2902278282 cites W2501822608 @default.
- W2902278282 cites W2505111109 @default.
- W2902278282 cites W2508812891 @default.
- W2902278282 cites W2559780630 @default.
- W2902278282 cites W2588167940 @default.
- W2902278282 cites W2589716041 @default.
- W2902278282 cites W2593241364 @default.
- W2902278282 cites W2605331601 @default.
- W2902278282 cites W2734430157 @default.
- W2902278282 cites W2737107694 @default.
- W2902278282 cites W2744248527 @default.
- W2902278282 cites W2768738707 @default.
- W2902278282 cites W2789791199 @default.
- W2902278282 cites W2791145742 @default.
- W2902278282 cites W2809692731 @default.
- W2902278282 cites W2883753534 @default.
- W2902278282 cites W2896504121 @default.
- W2902278282 cites W2896823132 @default.
- W2902278282 cites W2950417959 @default.
- W2902278282 cites W2950735744 @default.
- W2902278282 cites W2951666951 @default.
- W2902278282 doi "https://doi.org/10.1016/j.ijbiomac.2018.12.013" @default.
- W2902278282 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30521915" @default.
- W2902278282 hasPublicationYear "2019" @default.
- W2902278282 type Work @default.
- W2902278282 sameAs 2902278282 @default.
- W2902278282 citedByCount "14" @default.
- W2902278282 countsByYear W29022782822019 @default.
- W2902278282 countsByYear W29022782822020 @default.
- W2902278282 countsByYear W29022782822021 @default.
- W2902278282 countsByYear W29022782822022 @default.
- W2902278282 countsByYear W29022782822023 @default.
- W2902278282 crossrefType "journal-article" @default.
- W2902278282 hasAuthorship W2902278282A5004093347 @default.
- W2902278282 hasAuthorship W2902278282A5017362236 @default.
- W2902278282 hasAuthorship W2902278282A5022950764 @default.
- W2902278282 hasAuthorship W2902278282A5024669485 @default.
- W2902278282 hasAuthorship W2902278282A5033697778 @default.
- W2902278282 hasAuthorship W2902278282A5047297176 @default.
- W2902278282 hasAuthorship W2902278282A5069633552 @default.
- W2902278282 hasConcept C104779481 @default.
- W2902278282 hasConcept C127413603 @default.
- W2902278282 hasConcept C140205800 @default.
- W2902278282 hasConcept C154877778 @default.
- W2902278282 hasConcept C159985019 @default.
- W2902278282 hasConcept C161790260 @default.
- W2902278282 hasConcept C175708663 @default.
- W2902278282 hasConcept C178790620 @default.
- W2902278282 hasConcept C185592680 @default.
- W2902278282 hasConcept C192562407 @default.