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- W2902316516 abstract "The ligand [2,2′-bipyridin]-6(1H)-one (bipy-6-OH) has a strong accelerating effect on the Pd-catalyzed direct arylation of pyridine or arenes. The isolation of relevant intermediates and the study of their decomposition unequivocally show that the deprotonated coordinated ligand acts as a base and assists the cleavage of the C–H bond. Mechanistic work indicates that the direct arylation of pyridine with this ligand occurs through a Pd(0)/Pd(II) cycle. Because of this dual ligand–intramolecular base role, there is no need for an available coordination site on the metal for an external base, a difficulty encountered when chelating ligands are used in coupling reactions that involve a C–H cleavage step." @default.
- W2902316516 created "2018-12-11" @default.
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- W2902316516 date "2018-12-06" @default.
- W2902316516 modified "2023-10-14" @default.
- W2902316516 title "[2,2′-Bipyridin]-6(1<i>H</i>)-one, a Truly Cooperating Ligand in the Palladium-Mediated C–H Activation Step: Experimental Evidence in the Direct C-3 Arylation of Pyridine" @default.
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- W2902316516 doi "https://doi.org/10.1021/jacs.8b10680" @default.
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