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- W2902363578 abstract "Abstract Addition of DMSO is found to greatly accelerate the aqueous hydrolysis of organohalides to alcohols, providing a neutral, more efficient, milder and more economic process. Mechanistic studies using 18 O‐DMSO and 18 O‐H 2 O showed that, contrary to the opinion that DMSO works as a dipolar solvent to enhance water's nucleophilicity, the accelerating effect comes from a complete oxygen transfer from DMSO to organohalides through generation of ROS + Me 2 ⋅ X − salts through C−O bond formation, followed by O−S bond disassociative hydrolysis of ROS + Me 2 ⋅ X − with water. This method is applicable to a wide range of organohalides and thus may have potential for practical industrial application, owing to easy recovery of DMSO from the H 2 O/DMSO mixture by regular vacuum rectification." @default.
- W2902363578 created "2018-12-11" @default.
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- W2902363578 date "2018-12-20" @default.
- W2902363578 modified "2023-09-30" @default.
- W2902363578 title "DMSO‐Triggered Complete Oxygen Transfer Leading to Accelerated Aqueous Hydrolysis of Organohalides under Mild Conditions" @default.
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- W2902363578 doi "https://doi.org/10.1002/cssc.201802138" @default.
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