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- W2902376503 abstract "Lewis-acid-induced domino transformations of donor–acceptor cyclopropanes, possessing a nucleophilic center embedded in a donor group, into functionalized 2,3-dihydrobenzo[b]furans and 2,3-dihydrobenzo[b]thiophenes are reported herein. An unusual switch of the electrophilic center in the three-membered ring, from the atom bearing a donor substituent to an unsubstituted carbon atom, was achieved by a judicious choice of Lewis acid, which induces the isomerization of a cyclopropane to an electrophilic alkene, and the length of linker, connecting a nucleophilic moiety and the small ring." @default.
- W2902376503 created "2018-12-11" @default.
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- W2902376503 creator A5080867162 @default.
- W2902376503 creator A5087087375 @default.
- W2902376503 date "2018-12-05" @default.
- W2902376503 modified "2023-10-14" @default.
- W2902376503 title "Expanding the Reactivity of Donor–Acceptor Cyclopropanes: Synthesis of Benzannulated Five-Membered Heterocycles via Intramolecular Attack of a Pendant Nucleophilic Group" @default.
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- W2902376503 doi "https://doi.org/10.1021/acs.orglett.8b03491" @default.
- W2902376503 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30517005" @default.
- W2902376503 hasPublicationYear "2018" @default.
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