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- W2902493043 abstract "8-Allylcoumarins are conveniently accessible through a microwave-promoted tandem Claisen rearrangement/Wittig olefination/cyclization sequence. They serve as a versatile platform for the annellation of five- to seven-membered rings using ring-closing olefin metathesis (RCM). Furano-, pyrano-, oxepino- and azepinocoumarins were synthesized from the same set of precursors using Ru-catalyzed double bond isomerizations and RCM in a defined order. One class of products, pyrano[2,3- f ]chromene-2,8-diones, were inaccessible through direct RCM of an acrylate, but became available from the analogous allyl ether via an assisted tandem catalytic RCM/allylic oxidation sequence." @default.
- W2902493043 created "2018-12-11" @default.
- W2902493043 creator A5026951945 @default.
- W2902493043 creator A5048027528 @default.
- W2902493043 date "2018-12-05" @default.
- W2902493043 modified "2023-10-18" @default.
- W2902493043 title "Ring-closing-metathesis-based synthesis of annellated coumarins from 8-allylcoumarins" @default.
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- W2902493043 doi "https://doi.org/10.3762/bjoc.14.278" @default.
- W2902493043 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6296409" @default.
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