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- W2902569715 abstract "The oxazolidinone as one kind of annular CO2 derivatives has been hydrogenated by a new catalytic system Pd/C-TMGPEG150Me (polyethylene glycol-functionalized 1,1,3,3-tetramethyl guanidine), affording two valuable products i.e. formic acid and the corresponding secondary alkyl-(2-arylethyl)amines in the high yields of 89% and 98%, respectively. This hydrogenation can be carried out smoothly under relatively mild conditions of 60 °C, 4 MPa of H2 with a liquid/solid carbon source (oxazolidinone) instead of high pressure CO2. The notable results can be successfully obtained even at room temperature under atmospheric H2 pressure. This one stone two bird strategy is applicable to series of 5-aryl-2-oxazolidinones and opens up a novel way of synthesizing linear secondary alkyl-(2-arylethyl)amines without the selectivity issues, and validates a potential alternative approach for indirect conversion of CO2 to energy-related products formic acid, as oxazolidinones can be readily obtained from hydrogenation of CO2." @default.
- W2902569715 created "2018-12-11" @default.
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- W2902569715 date "2019-01-01" @default.
- W2902569715 modified "2023-10-09" @default.
- W2902569715 title "An alternative route of CO2 conversion: Pd/C-catalyzed oxazolidinone hydrogenation to HCOOH and secondary alkyl-(2-arylethyl)amines with one stone two bird strategy" @default.
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- W2902569715 doi "https://doi.org/10.1016/j.jcou.2018.11.009" @default.
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