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- W2902622472 abstract "A series of open-tip carbon nanotubes (CNTs) were obtained by HNO 3 modification with various concentrations of as-prepared carbon nanotubes via the CVD method, and this work aimed at investigating the structural features of open-tip CNTs for the methane capability. Modified CNTs had higher specific surface area and larger total pore volume, and importantly, greater micropore volume was obtained through HNO 3 modification of the as-prepared CNTs. The remarkably high methane adsorption capacities were measured on the modified CNTs under pressure ranges of 0∼4.0 MPa at 298 K. The resulted H-CNT, which exhibited highest specific surface area and micropore volume, showed high methane uptake of 26.15 mg/g from the D-A model. This value was nearly as twice as the methane uptake of original CNTs (13.62 mg/g), along with an initial adsorption heat of 19.4 kJ/mol at lower coverage and 9.5 kJ/mol at higher methane coverage for H-CNT, indicating the physical nature for methane adsorption over open-tip CNTs." @default.
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- W2902622472 date "2018-11-26" @default.
- W2902622472 modified "2023-10-16" @default.
- W2902622472 title "Open-Tip Carbon Nanotubes for Enhanced Methane Adsorption Performance: A Comparative Study" @default.
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- W2902622472 doi "https://doi.org/10.1155/2018/8905204" @default.
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