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• W2902675176 abstract "Removal of chloride from CoCl2 with TlPF6 in acetonitrile, followed by addition of excess nitrosobenzene, yielded the eight-coordinate cobalt(II) complex salt [Co{Ph(O)NN(O)Ph}4](PF6)2, shown by single-crystal X-ray analysis to have a distorted tetragonal geometry. The analogous treatment of the bipyridyl complex Co(bpy)Cl2 yielded the mixed-ligand cobalt(II) complex salt [Co(bpy){Ph(O)NN(O)Ph}2](PF6)2, whose single-crystal X-ray structure displays a trigonal prismatic geometry, similar to that of the iron(II) cation in the previously known complex salt [Fe{Ph(O)NN(O)Ph}3](FeCl4)2. The use of TlPF6 to generate solvated metal complex cations from chloride salts or chlorido complexes, followed by the addition of nitrosobenzene, is shown to be a useful synthetic strategy for the preparation of azodioxide complex cations with the noncoordinating, diamagnetic PF6– counteranion. Coordination number appears to be more important than d electron count in determining the geometry and metal–ligand bond distances of diphenylazodioxide complexes." @default.
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• W2902675176 date "2018-11-27" @default.
• W2902675176 modified "2023-10-18" @default.
• W2902675176 title "Synthesis and Characterization of Cobalt(II) <i>N</i>,<i>N</i>′-Diphenylazodioxide Complexes" @default.
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• W2902675176 doi "https://doi.org/10.1021/acsomega.8b01200" @default.
• W2902675176 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6643636" @default.
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