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- W2902873040 abstract "Anionic hydridosilicates are highly reactive and strong hydride donors. In contrast, calix[4]pyrrole hydridosilicate is an entirely water-stable, anionic silicon hydride, which does not show hydridic reactivity. However, it still acts as an electron donor and enables the detection of a single electron transfer process in the reduction chemistry with hydridosilicates. Most important, these unusual properties are imparted by the unique planar structure of its elusive parent neutral silane-substantiating the effect of planar tetracoordinate silicon for the first time." @default.
- W2902873040 created "2018-12-11" @default.
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- W2902873040 creator A5054928447 @default.
- W2902873040 date "2018-11-30" @default.
- W2902873040 modified "2023-10-17" @default.
- W2902873040 title "Calix[4]pyrrole Hydridosilicate: The Elusive Planar Tetracoordinate Silicon Imparts Striking Stability to Its Anionic Silicon Hydride" @default.
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- W2902873040 doi "https://doi.org/10.1021/jacs.8b11137" @default.
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- W2902873040 hasPublicationYear "2018" @default.
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