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• W2902943324 abstract "Abstract For the first time, we determined the detailed crystal structure of Na 3 Sm(PO 4 ) 2 using single crystal X-ray diffraction and established the commensurately modulated structure model using the superspace formalism. The structure adopts a (3+1)-dimensional superspace group Pca 2 1 (0 β 0)000 with the modulation vector q=1/3b*. At the same time, the photoluminescent properties of Na 3 Sm(PO 4 ) 2 sintered at different temperatures between 800 and 1200°C were studied. Under near-UV excitation (402 nm), Na 3 Sm(PO 4 ) 2 shows intense characteristic emission bands of Sm 3+ (561, 596, 642 nm) with the CIE coordinate of (0.5709, 0.4282), corresponding to orange color. The excitation spectrum covers a wide range from 350 nm to 470 nm, which indicates that Na 3 Sm(PO 4 ) 2 can be efficiently activated by near-UV or visuable LED ship." @default.
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• W2902943324 date "2018-12-04" @default.
• W2902943324 modified "2023-09-23" @default.
• W2902943324 title "Na₃Sm(PO₄)₂: (3+1)-dimensional commensurately modulated structure model and photoluminescence properties" @default.
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• W2902943324 doi "https://doi.org/10.1515/zkri-2018-2095" @default.
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