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- W2903408051 abstract "Following the establishment of graphene quantum dots as potential phthalocyanine supports in photoactive membrane preparation for phthalocyanines lacking linkage functional groups, the practical efficiency of π-π stacking versus covalent linkage was investigated. Synthesized materials were characterized using FT-IR, Raman, powder X-ray diffraction, and UV–Vis spectroscopies and also by transmission electron and scanning electron microscopies. Phthalocyanine loadings onto graphene quantum dots of 0.40 mg/mg and 0.14 mg/mg (Pc mass/conjugate mass) for the π-π stacked and covalent linked conjugates respectively were observed. Covalent linkage to graphene quantum dots proved to be functionally superior to π-π linkage, where singlet oxygen quantum yield value of the phthalocyanine in the membrane for the covalent linked conjugate was approximately twice that of the π-π stacked membrane." @default.
- W2903408051 created "2018-12-11" @default.
- W2903408051 creator A5033870636 @default.
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- W2903408051 date "2019-03-01" @default.
- W2903408051 modified "2023-09-25" @default.
- W2903408051 title "A comparative study of the singlet oxygen generation capability of a zinc phthalocyanine linked to graphene quantum dots through π-π stacking and covalent conjugation when embedded in asymmetric polymer membranes" @default.
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- W2903408051 doi "https://doi.org/10.1016/j.molstruc.2018.11.096" @default.
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