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- W2903453312 abstract "Tame d0 phosphidotitanocene cations stabilized with a pendant tertiary phosphane arm are reported. These compounds were obtained by one-electron oxidation of d1 precursors with [Cp2 Fe][BPh4 ]. The electronic structure of these compounds was studied experimentally (EPR, UV/Vis, and NMR spectroscopy, X-ray diffraction analysis) and through DFT calculations. The theoretical analysis of the bonding situation by using the electron localization function (ELF) shows the presence of π-interactions between the phosphido ligand and Ti in the d0 complexes, whereas dπ-pπ repulsion prevents such interactions in the d1 complexes. In addition, CH-π interactions were observed in several complexes, both in solution and in the solid state, between the phosphido ligand and the phosphane arm. The d0 complexes were found to be light sensitive, and decompose through Ti-P bond homolysis to give TiIII species. A naked d0 phosphidotitanocene cation has been trapped by reaction with diphenylacetylene, yielding a Ti/P frustrated Lewis pair (FLP), which was found to be less reactive than a previously reported Zr analog." @default.
- W2903453312 created "2018-12-11" @default.
- W2903453312 creator A5001680084 @default.
- W2903453312 creator A5034807035 @default.
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- W2903453312 creator A5079926257 @default.
- W2903453312 creator A5084447043 @default.
- W2903453312 date "2019-01-29" @default.
- W2903453312 modified "2023-10-09" @default.
- W2903453312 title "The Taming of Redox‐Labile Phosphidotitanocene Cations" @default.
- W2903453312 cites W1786995775 @default.
- W2903453312 cites W1838080446 @default.
- W2903453312 cites W1910650343 @default.
- W2903453312 cites W1964752699 @default.
- W2903453312 cites W1965100696 @default.
- W2903453312 cites W1969730491 @default.
- W2903453312 cites W1970504980 @default.
- W2903453312 cites W1971636666 @default.
- W2903453312 cites W1974699143 @default.
- W2903453312 cites W1976195721 @default.
- W2903453312 cites W1979697474 @default.
- W2903453312 cites W1982520376 @default.
- W2903453312 cites W1985420479 @default.
- W2903453312 cites W1986928757 @default.
- W2903453312 cites W1988091937 @default.
- W2903453312 cites W1989854295 @default.
- W2903453312 cites W1990783422 @default.
- W2903453312 cites W1993315385 @default.
- W2903453312 cites W1993547462 @default.
- W2903453312 cites W1997151511 @default.
- W2903453312 cites W1997725714 @default.
- W2903453312 cites W1998936675 @default.
- W2903453312 cites W1999950260 @default.
- W2903453312 cites W2000539818 @default.
- W2903453312 cites W2001495654 @default.
- W2903453312 cites W2003973857 @default.
- W2903453312 cites W2005683065 @default.
- W2903453312 cites W2009600966 @default.
- W2903453312 cites W2012657941 @default.
- W2903453312 cites W2012760972 @default.
- W2903453312 cites W2017549559 @default.
- W2903453312 cites W2018990854 @default.
- W2903453312 cites W2020636734 @default.
- W2903453312 cites W2021716277 @default.
- W2903453312 cites W2022098548 @default.
- W2903453312 cites W2023592695 @default.
- W2903453312 cites W2024809349 @default.
- W2903453312 cites W2027475027 @default.
- W2903453312 cites W2029667189 @default.
- W2903453312 cites W2032587760 @default.
- W2903453312 cites W2036362992 @default.
- W2903453312 cites W2039579891 @default.
- W2903453312 cites W2040261022 @default.
- W2903453312 cites W2040398868 @default.
- W2903453312 cites W2042599059 @default.
- W2903453312 cites W2049969416 @default.
- W2903453312 cites W2052345427 @default.
- W2903453312 cites W2055172042 @default.
- W2903453312 cites W2055608325 @default.
- W2903453312 cites W2056222234 @default.
- W2903453312 cites W2060898892 @default.
- W2903453312 cites W2067889032 @default.
- W2903453312 cites W2070865005 @default.
- W2903453312 cites W2071383781 @default.
- W2903453312 cites W2082705474 @default.
- W2903453312 cites W2086904877 @default.
- W2903453312 cites W2087128022 @default.
- W2903453312 cites W2088222298 @default.
- W2903453312 cites W2088440532 @default.
- W2903453312 cites W2088901706 @default.
- W2903453312 cites W2096915625 @default.
- W2903453312 cites W2097574296 @default.
- W2903453312 cites W2099417736 @default.
- W2903453312 cites W2100330046 @default.
- W2903453312 cites W2103812313 @default.
- W2903453312 cites W2113701650 @default.
- W2903453312 cites W2114017521 @default.
- W2903453312 cites W2115797118 @default.
- W2903453312 cites W2119547517 @default.
- W2903453312 cites W2121237359 @default.
- W2903453312 cites W2142796813 @default.
- W2903453312 cites W2168265920 @default.
- W2903453312 cites W2257179066 @default.
- W2903453312 cites W2265526452 @default.
- W2903453312 cites W2270838075 @default.
- W2903453312 cites W2273226268 @default.
- W2903453312 cites W2320534486 @default.
- W2903453312 cites W2328976735 @default.
- W2903453312 cites W2395498657 @default.
- W2903453312 cites W2516795885 @default.
- W2903453312 cites W2584559394 @default.
- W2903453312 cites W2950385843 @default.
- W2903453312 cites W2950781819 @default.