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• W2903557726 abstract "Abstract Side‐chain‐type sulfonated/quaternized aromatic polyelectrolytes with precisely controlled contents of ionized groups are successfully synthesized via direct polyacylation of sulfonated/quaternized monomers based on 2,2′‐dihydroxy‐1,1′‐binaphthyl (DHBN). Both proton exchange membranes (PEMs) and anion exchange membranes (AEMs) of the corresponding polyelectrolytes exhibit outstanding properties. Proton conductivity (116 mS cm −1 at 30 °C) higher than Nafion 115 for the PEMs and OH – conductivity (28.5–53.7 mS cm −1 at 30 °C) comparable to Tokuyama A901 for the AEMs are accomplished. In addition, the AEMs can withstand 60 days’ aging in 1 mol L −1 NaOH at 60 °C without degradation, as proved by 1 H NMR. More intriguingly, when starting from optically active ( S )‐DHBN instead of racemic DHBN, an enhancement in proton conductivity of PEMs is observed for the first time, which opens a new door to optically active ion exchange membranes." @default.
• W2903557726 created "2018-12-11" @default.
• W2903557726 creator A5011788131 @default.
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• W2903557726 date "2018-12-04" @default.
• W2903557726 modified "2023-10-16" @default.
• W2903557726 title "High Performance Ion Exchange Membranes Prepared via Direct Polyacylation of Racemic and (S)‐1,1′‐Binaphthyl‐Based Cationic/Anionic Monomers" @default.
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• W2903557726 doi "https://doi.org/10.1002/mame.201800547" @default.
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