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- W2903583008 abstract "A complementing Pd- and Rh-catalyzed dynamic kinetic resolution (DKR) of racemic allenes leading to N-allylated pyrazoles is described. Such compounds are of enormous interest in medicinal chemistry as certified drugs and potential drug candidates. The new methods feature high chemo-, regio- and enantioselectivities aside from displaying a broad substrate scope and functional group compatibility. A mechanistic rational accounting for allene racemization and trans-alkene selectivity is discussed." @default.
- W2903583008 created "2018-12-22" @default.
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- W2903583008 date "2019-03-11" @default.
- W2903583008 modified "2023-10-02" @default.
- W2903583008 title "Palladium‐ and Rhodium‐Catalyzed Dynamic Kinetic Resolution of Racemic Internal Allenes Towards Chiral Pyrazoles" @default.
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- W2903583008 doi "https://doi.org/10.1002/anie.201812984" @default.
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