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• W2903590741 startingPage "3369" @default.
• W2903590741 abstract "Development of supramolecular methods to further activate a highly reactive intermediate is a fascinating strategy to create novel potent catalysts for activation of inert chemicals. Herein, a supramolecular approach to enhance the oxidizing ability of a high-valent oxo species of a nitrido-bridged iron porphyrinoid dimer that is a known potent molecular catalyst for light alkane oxidation is reported. For this purpose, a nitrido-bridged dinuclear iron complex of porphyrin-phthalocyanine heterodimer 35+ , which is connected through a fourfold rotaxane, was prepared. Heterodimer 35+ catalyzed ethane oxidation in the presence of H2 O2 at a relatively low temperature. The site-selective complexation of 35+ with an additional anionic porphyrin (TPPS4- ) through π-π stacking and electrostatic interactions afforded a stable 1:1 complex. It was demonstrated that the supramolecular post-synthetic modification of 35+ enhances its catalytic activity efficiently. Moreover, supramolecular conjugates achieved higher catalytic ethane oxidation activity than nitrido-bridged iron phthalocyanine dimer, which is the most potent iron-oxo-based molecular catalyst for light-alkane oxidation reported so far. Electrochemical measurements proved that the electronic perturbation from TPPS4- to 35+ enhanced the catalytic activity." @default.
• W2903590741 created "2018-12-22" @default.
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• W2903590741 date "2019-02-07" @default.
• W2903590741 modified "2023-09-25" @default.
• W2903590741 title "Site‐Selective Supramolecular Complexation Activates Catalytic Ethane Oxidation by a Nitrido‐Bridged Iron Porphyrinoid Dimer" @default.
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• W2903590741 doi "https://doi.org/10.1002/chem.201805580" @default.
• W2903590741 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30548706" @default.
• W2903590741 hasPublicationYear "2019" @default.
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