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- W2903681445 abstract "Chemocatalysis of sugars to methyl lactate (MLA) exhibits great advantages over the conventional fermentation approach because of its higher productivity and cost-effective separation process. However, widely used supported metal oxide catalysts suffer from deactivation resulting from sintering during the reaction and removal of coke at high temperatures. Herein, we report ultrasmall cobalt oxide clusters (∼1.7 nm) stabilized within silicalite-1 crystals catalyst (CoO@silicalite-1), exhibiting superior catalytic activity and resistance to sintering for the conversion of fructose into methyl lactate. HAADF-STEM, EDS-mapping, and XRD experiments identify the existence of confined CoO clusters. XANES and Raman spectra demonstrated the covalent interaction between CoO and silicalite-1. Thanks to the ultrasmall CoO particle size (∼1.7 nm), the CoO@silicalite-1 affords nearly 100-fold higher Co-mass-based activity (mg MLA/mg Co) compared with CoO or Co3O4 particles outside the silicalite-1 framework. More impor..." @default.
- W2903681445 created "2018-12-22" @default.
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- W2903681445 date "2018-12-13" @default.
- W2903681445 modified "2023-10-01" @default.
- W2903681445 title "Confinement of Ultrasmall Cobalt Oxide Clusters within Silicalite-1 Crystals for Efficient Conversion of Fructose into Methyl Lactate" @default.
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- W2903681445 doi "https://doi.org/10.1021/acscatal.8b03230" @default.
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