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• W2903755832 abstract "A general and efficient Ni-catalyzed coupling of challenging aryl chlorides and in situ generated aliphatic and aromatic thiolates is described. The employed on-cycle, air-stable defined Ni precatalysts allow for transformation of a broad scope of substrates. A variety of functional groups and heterocyclic motifs as well as structurally varied thiols are tolerated at unprecedented moderate catalyst loadings and reaction temperatures. Depending on reaction conditions, aryl thiols can selectively undergo C–S or C–C couplings." @default.
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• W2903755832 date "2018-12-17" @default.
• W2903755832 modified "2023-10-13" @default.
• W2903755832 title "Cross-Coupling of Chloro(hetero)arenes with Thiolates Employing a Ni(0)-Precatalyst" @default.
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• W2903755832 doi "https://doi.org/10.1021/acs.orglett.8b03476" @default.
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