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- W2903789632 abstract "Abstract Benzoaceanthrylene analogs with tetracoordinate boron at the ring junction were synthesized through tandem electrophilic C−H borylation of 2,6‐dinaphthylpyridine followed by nucleophilic substitution. Notably, the [5,6]‐annulation occurred selectively over [6,6]‐annulation with the assistance of nitrogen coordination of the pyridine ring. The X‐ray crystallographic analysis revealed the polycyclic skeleton with a distorted tetracoordinate boron atom and a unique packing structure with intermolecular π–π interaction. The photophysical and electrochemical properties of these benzoaceanthrylene analogs were evaluated by UV‐vis spectroscopy and differential pulse voltammetry. The electron affinity of the fluorine‐substituted derivative is estimated to be 3.49 eV from the ionization potential and optical band gap. Thus, this derivative is expected to be a promising n‐type semiconducting material." @default.
- W2903789632 created "2018-12-22" @default.
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- W2903789632 creator A5067377274 @default.
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- W2903789632 date "2019-01-04" @default.
- W2903789632 modified "2023-09-25" @default.
- W2903789632 title "Synthesis of Tetracoordinate Boron‐Fused Benzoaceanthrylene Analogs via Tandem Electrophilic C−H Borylation" @default.
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- W2903789632 doi "https://doi.org/10.1002/asia.201801682" @default.
- W2903789632 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30548227" @default.
- W2903789632 hasPublicationYear "2019" @default.
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