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• W2903799720 startingPage "79" @default.
• W2903799720 abstract "Abstract Enantioselective vinylation of aldehydes via direct catalytic asymmetric Grignard reaction of aldehdyes and the vinyl Grinard reagent is a long‐standing challenge. This work demonstrated that the magnesium ( S )‐3,3′‐dimethyl BINOLate enantioselectively catalyze the direct vinylation of aldehydes with the deactivated vinylmagnesium bromide by bis(2‐[ N,N ′‐dimethylamino]ethyl) ether (BDMAEE) in the addition of n ‐butylmagnesium chloride. The highest ee of 63% was achieved up to date." @default.
• W2903799720 created "2018-12-22" @default.
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• W2903799720 date "2018-12-06" @default.
• W2903799720 modified "2023-09-26" @default.
• W2903799720 title "Enantioselective vinylation of aldehydes with the vinyl Grignard reagent catalyzed by magnesium complex of chiral BINOLs" @default.
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• W2903799720 doi "https://doi.org/10.1002/chir.23038" @default.
• W2903799720 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30520127" @default.
• W2903799720 hasPublicationYear "2018" @default.
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