FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2903938436> ?p ?o ?g. }

• W2903938436 endingPage "18" @default.
• W2903938436 startingPage "7" @default.
• W2903938436 abstract "It is commonly known that flexible structures and movable substituents are unfavorable for realizing intense luminescence with organic dyes. On the other hand, we show in this short review that excitation-driven boron complexes are promising platforms for obtaining stimuli-responsive luminescent materials with high sensitivity. Initially, we explained transformation of the valence of boron in heterofluorene from four to three-coordinate state through excitation-driven bond cleavage at the boron dative bond. The mechanism and stimuli-responsive luminescence with high sensitivity are illustrated. The next topic regards rational design of aggregation-induced emission (AIE)-active molecules, which are able to provide enhanced emission by aggregation. By employing theoretical calculations, it was possible to find a series of novel AIE-active skeletons from scratch. Stimuli-responsive luminescent chromism was also observed from the resulting molecules. The final topic is concerned with aryl–o-carborane dyads. It was recently found that rotation of the o-carborane unit proceeds triggered by photo-excitation. By regulating rotation behaviors, not only solid-state luminescence but also dual emission were obtained. The concept and several examples to offer applications of this new class of boron complexes are reviewed. The concept of excitation-driven boron complexes, which show potentially large structural transformation in the excited state, and their applications as functional luminescent materials are illustrated. Due to poor luminescent ability, these complexes have not been utilized as an optical material, meanwhile, recent reports suggest great versatility of these complexes as a platform for constructing stimuli-responsive luminescent materials with high sensitivity. We summarize recent progress in this review." @default.
• W2903938436 created "2018-12-22" @default.
• W2903938436 creator A5011132235 @default.
• W2903938436 creator A5036531859 @default.
• W2903938436 creator A5073553496 @default.
• W2903938436 date "2019-01-15" @default.
• W2903938436 modified "2023-10-17" @default.
• W2903938436 title "Concept of Excitation-Driven Boron Complexes and Their Applications for Functional Luminescent Materials" @default.
• W2903938436 cites W1665070293 @default.
• W2903938436 cites W1800508791 @default.
• W2903938436 cites W1862988383 @default.
• W2903938436 cites W1909050858 @default.
• W2903938436 cites W1966779172 @default.
• W2903938436 cites W1993608226 @default.
• W2903938436 cites W2000296205 @default.
• W2903938436 cites W2007278339 @default.
• W2903938436 cites W2007942409 @default.
• W2903938436 cites W2008997596 @default.
• W2903938436 cites W2023101016 @default.
• W2903938436 cites W2026577145 @default.
• W2903938436 cites W2032185182 @default.
• W2903938436 cites W2039252107 @default.
• W2903938436 cites W2040402142 @default.
• W2903938436 cites W2043716858 @default.
• W2903938436 cites W2050410122 @default.
• W2903938436 cites W2053053575 @default.
• W2903938436 cites W2066290441 @default.
• W2903938436 cites W2069130585 @default.
• W2903938436 cites W2070370924 @default.
• W2903938436 cites W2070764945 @default.
• W2903938436 cites W2072408396 @default.
• W2903938436 cites W2091783956 @default.
• W2903938436 cites W2091901190 @default.
• W2903938436 cites W2098999559 @default.
• W2903938436 cites W2099699801 @default.
• W2903938436 cites W2113981935 @default.
• W2903938436 cites W2114135740 @default.
• W2903938436 cites W2135249530 @default.
• W2903938436 cites W2137339007 @default.
• W2903938436 cites W2139838890 @default.
• W2903938436 cites W2144484723 @default.
• W2903938436 cites W2146422134 @default.
• W2903938436 cites W2156592199 @default.
• W2903938436 cites W2161275945 @default.
• W2903938436 cites W2164092379 @default.
• W2903938436 cites W2177603935 @default.
• W2903938436 cites W2271409444 @default.
• W2903938436 cites W2291993791 @default.
• W2903938436 cites W2303153210 @default.
• W2903938436 cites W2313742827 @default.
• W2903938436 cites W2314807620 @default.
• W2903938436 cites W2315380494 @default.
• W2903938436 cites W2317121134 @default.
• W2903938436 cites W2319551386 @default.
• W2903938436 cites W2325025064 @default.
• W2903938436 cites W2325713496 @default.
• W2903938436 cites W2328613312 @default.
• W2903938436 cites W2328987331 @default.
• W2903938436 cites W2329383769 @default.
• W2903938436 cites W2331751649 @default.
• W2903938436 cites W2331853219 @default.
• W2903938436 cites W2333594446 @default.
• W2903938436 cites W2335534965 @default.
• W2903938436 cites W2345178354 @default.
• W2903938436 cites W2355905379 @default.
• W2903938436 cites W2406091788 @default.
• W2903938436 cites W2478148051 @default.
• W2903938436 cites W2481270146 @default.
• W2903938436 cites W2516046034 @default.
• W2903938436 cites W2523130099 @default.
• W2903938436 cites W2553234455 @default.
• W2903938436 cites W2553518572 @default.
• W2903938436 cites W2555045739 @default.
• W2903938436 cites W2555547891 @default.
• W2903938436 cites W2558174366 @default.
• W2903938436 cites W2558822712 @default.
• W2903938436 cites W2588617764 @default.
• W2903938436 cites W2604184660 @default.
• W2903938436 cites W2613713936 @default.
• W2903938436 cites W2622779288 @default.
• W2903938436 cites W2623182463 @default.
• W2903938436 cites W2701840719 @default.
• W2903938436 cites W2715456463 @default.
• W2903938436 cites W2719240986 @default.
• W2903938436 cites W2722466994 @default.
• W2903938436 cites W2749127170 @default.
• W2903938436 cites W2754512053 @default.
• W2903938436 cites W2755167391 @default.
• W2903938436 cites W2757747468 @default.
• W2903938436 cites W2758697569 @default.
• W2903938436 cites W2770834724 @default.
• W2903938436 cites W2772432453 @default.
• W2903938436 cites W2781661053 @default.
• W2903938436 cites W2783248254 @default.
• W2903938436 cites W2784250129 @default.
• W2903938436 cites W2787825754 @default.
• W2903938436 cites W2788947308 @default.
• W2903938436 cites W2789265281 @default.

• next