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• W2903950500 abstract "Abstract Ni and B in the Ni-B coated Ti (Ti@Ni-B) core-shell powders fabricated by electroless plating are present in the form of intergrowth of crystals consisting of amorphous Ni-B alloy and Ni3B compounds, which therefore modified the reaction path and liquid formation process. In-situ sintering microstructure evolution indicated that the activation of B as a sintering aid started with the way that Ni and B from coated amorphous Ni-B reacted to form low-melting Ni3B compounds prior to the formation of Ti2Ni between Ni and Ti. Both low-melting-point compounds were melted to form liquid and significantly increased the amount of liquid by which the sintering densification was enhanced. Another positive role of using Ti@Ni-B powders was the in-situ formation of TiB on each Ti particle by which a high number density of low-energy-barrier heterogeneous nucleation sites and pinning points were produced. This resulted in finer grain and better equiaxed crystallization. The enhanced sintering densification contributed to the improved tensile strength while a combination of the equiaxed α-Ti grains, low oxygen increment and reduced porosity were responsible for the increased tensile ductility by 60%." @default.
• W2903950500 created "2018-12-22" @default.
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• W2903950500 date "2019-03-01" @default.
• W2903950500 modified "2023-09-28" @default.
• W2903950500 title "Activation of B as a sintering aid and its improved microstructure modification by using Ni-B coated Ti core-shell powder" @default.
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• W2903950500 doi "https://doi.org/10.1016/j.mtla.2018.100182" @default.
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