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- W2904001561 endingPage "733" @default.
- W2904001561 startingPage "726" @default.
- W2904001561 abstract "Carbocyclic carbenes (CCCs) are a class of nucleophilic carbenes which are very similar to N ‐heterocyclic carbenes (NHCs) in terms of their reactivity, but they do not contain a stabilizing heteroatom in their cyclic ring system. In this study, 17 representative known CCCs and 34 newly designed CCCs are evaluated using quantum chemical methods, and the results are compared in terms of their stability, nucleophilicity, and proton affinity (PA) parameters. The results are divided on the basis of ring size of the known and reported CCCs. The stability, nucleophilicity, PA, complexation energy, and bond strength–related parameters were estimated using M06/6‐311++G(d,p) method. The results indicated that the CCCs known in the literature are strong σ‐electron donating species and have considerable π‐accepting properties. This study led to the design and identification of a few new CCCs with dimethylamine and diaminomethynyl substituents which can be singlet stable and are substantially nucleophilic. © 2018 Wiley Periodicals, Inc." @default.
- W2904001561 created "2018-12-22" @default.
- W2904001561 creator A5010723907 @default.
- W2904001561 creator A5020462993 @default.
- W2904001561 creator A5022043650 @default.
- W2904001561 creator A5038348983 @default.
- W2904001561 creator A5065218199 @default.
- W2904001561 date "2018-12-14" @default.
- W2904001561 modified "2023-10-05" @default.
- W2904001561 title "Electronic and ligating properties of carbocyclic carbenes: A theoretical investigation" @default.
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