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- W2904005708 abstract "The widespread occurrence of a large variety of long chain fattyacids has encouraged considerable investigation into the methods by whichthey are biosynthesised. The overall mechanisms of many of these pathwayshave been elucidated, but much remains to be discovered about the absolutestereochemistry of these reactions. This thesis describes work carriedout to help define the stereochemistry of some of these reactions.To investigate the stereochemistry of two of the intermediate stepsof chain elongation in fatty acid biosynthesis, the synthesis of αβ-unsaturatedand β-hydroxy fatty acids specifically labelled with eithertritium or deuterium was undertaken. The incubation of these labelledacids with the green algae Chlorella vulgaris allowed the absolute stereospecificityof the dehydration and hydrogenation steps of acyl chainelongation to be determined. [Continues.]" @default.
- W2904005708 created "2018-12-22" @default.
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- W2904005708 date "1974-01-01" @default.
- W2904005708 modified "2023-09-24" @default.
- W2904005708 title "The stereochemistry and metabolism of fatty acids in plants" @default.
- W2904005708 hasPublicationYear "1974" @default.
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