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• W2904032407 abstract "Several six-coordinate iron(II) carbene tetra(pentafluorophenyl)porphyrin (TFPP) complexes, [Fe(TFPP)(CPh2)(1-EtIm)] (1-EtIm = 1-ethylimidazole) and [Fe(TFPP)(CPh2)(1,2-Me2Im)] (1,2-Me2Im = 1,2-dimethylimidazole), are isolated and studied by UV–vis, single-crystal X-ray, and Mössbauer spectroscopies. The single-crystal structural studies revealed noteworthy features including strong and “hard” axial carbene bonds (Fe–C) but “flexible” trans ligand bonds (Fe–NIm). The Mössbauer spectra of [Fe(TFPP)(CPh2)(1-EtIm)] and [Fe(TFPP)(CPh2)(1,2-Me2Im)] are obtained on solid-state samples between 25 and 295 K, which give very large ΔEQ values (1.8–1.9 mm/s), suggesting a weak effect of the trans imidazole ligands. Comparisons with diatomic carbon-donor ligands (CO, CS, and CN–) demonstrate considerably stronger π bonding of the :CPh2 carbene." @default.
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• W2904032407 date "2018-12-19" @default.
• W2904032407 modified "2023-09-23" @default.
• W2904032407 title "New Insights into the Ligand Nature of Carbene: Synthesis and Characterizations of Six-Coordinate Iron(II) Carbene Porphyrin Complexes" @default.
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• W2904032407 doi "https://doi.org/10.1021/acs.inorgchem.8b02043" @default.
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