Matches in SemOpenAlex for { <https://semopenalex.org/work/W2904042080> ?p ?o ?g. }
Showing items 1 to 98 of
98
with 100 items per page.
- W2904042080 endingPage "1255" @default.
- W2904042080 startingPage "1244" @default.
- W2904042080 abstract "Abstract Rate measurements in the kinetically controlled regime and equilibrium carbon and oxygen chemical titrations show two distinct mechanistic paths during CO x methanation reactions on first‐row transition metal clusters. On Ni and, for a limiting set of conditions, Ni−Co clusters, the reaction occurs via the addition of a hydrogen adatom into CH 3 * intermediates on clusters partially covered with carbon. On Co and, in a subset of conditions, Ni−Co clusters, it occurs via the donation of hydrogen from OH* to CH 3 * on clusters partially covered with reactive oxygen adatoms (O*). The [CO] 2 ‐to‐[CO 2 ] and [CO 2 ]‐to‐[CO] operating ratios are the surrogates of carbon and oxygen chemical potentials, respectively, as a consequence of water‐gas shift equilibration. These ratios, together with the carbon and oxygen binding energies, determine the relative surface coverages of carbon and oxygen, the involvement of H* vs. OH* in the kinetically‐relevant step, and in turn, the rate dependencies. Stronger carbon and oxygen binding energies lead to more stabilized transition states of the kinetically relevant steps and larger methanation rates." @default.
- W2904042080 created "2018-12-22" @default.
- W2904042080 creator A5039229575 @default.
- W2904042080 creator A5082933171 @default.
- W2904042080 date "2019-01-30" @default.
- W2904042080 modified "2023-09-25" @default.
- W2904042080 title "Influence of Carbon and Oxygen Chemical Potentials on the Hydrogen Donor Identity during Methanation on Ni, Co, and Ni‐Co Clusters" @default.
- W2904042080 cites W1969324223 @default.
- W2904042080 cites W1971467511 @default.
- W2904042080 cites W1976310442 @default.
- W2904042080 cites W1980158088 @default.
- W2904042080 cites W1981859909 @default.
- W2904042080 cites W1989421746 @default.
- W2904042080 cites W1991630775 @default.
- W2904042080 cites W2002068140 @default.
- W2904042080 cites W2006248254 @default.
- W2904042080 cites W2007740449 @default.
- W2904042080 cites W2014907980 @default.
- W2904042080 cites W2017066647 @default.
- W2904042080 cites W2039425128 @default.
- W2904042080 cites W2041393814 @default.
- W2904042080 cites W2050190123 @default.
- W2904042080 cites W2058145461 @default.
- W2904042080 cites W2063619209 @default.
- W2904042080 cites W2079845692 @default.
- W2904042080 cites W2081717144 @default.
- W2904042080 cites W2089073320 @default.
- W2904042080 cites W2100460025 @default.
- W2904042080 cites W2105744137 @default.
- W2904042080 cites W2109664124 @default.
- W2904042080 cites W2111865195 @default.
- W2904042080 cites W2119741652 @default.
- W2904042080 cites W2120243442 @default.
- W2904042080 cites W2136135454 @default.
- W2904042080 cites W2153502737 @default.
- W2904042080 cites W2158161993 @default.
- W2904042080 cites W2515957200 @default.
- W2904042080 cites W4212894238 @default.
- W2904042080 cites W4234390125 @default.
- W2904042080 doi "https://doi.org/10.1002/cctc.201801545" @default.
- W2904042080 hasPublicationYear "2019" @default.
- W2904042080 type Work @default.
- W2904042080 sameAs 2904042080 @default.
- W2904042080 citedByCount "2" @default.
- W2904042080 countsByYear W29040420802020 @default.
- W2904042080 countsByYear W29040420802023 @default.
- W2904042080 crossrefType "journal-article" @default.
- W2904042080 hasAuthorship W2904042080A5039229575 @default.
- W2904042080 hasAuthorship W2904042080A5082933171 @default.
- W2904042080 hasConcept C104779481 @default.
- W2904042080 hasConcept C106773901 @default.
- W2904042080 hasConcept C123703457 @default.
- W2904042080 hasConcept C140205800 @default.
- W2904042080 hasConcept C159985019 @default.
- W2904042080 hasConcept C161790260 @default.
- W2904042080 hasConcept C178790620 @default.
- W2904042080 hasConcept C179104552 @default.
- W2904042080 hasConcept C185592680 @default.
- W2904042080 hasConcept C192562407 @default.
- W2904042080 hasConcept C512968161 @default.
- W2904042080 hasConcept C515602321 @default.
- W2904042080 hasConcept C540031477 @default.
- W2904042080 hasConceptScore W2904042080C104779481 @default.
- W2904042080 hasConceptScore W2904042080C106773901 @default.
- W2904042080 hasConceptScore W2904042080C123703457 @default.
- W2904042080 hasConceptScore W2904042080C140205800 @default.
- W2904042080 hasConceptScore W2904042080C159985019 @default.
- W2904042080 hasConceptScore W2904042080C161790260 @default.
- W2904042080 hasConceptScore W2904042080C178790620 @default.
- W2904042080 hasConceptScore W2904042080C179104552 @default.
- W2904042080 hasConceptScore W2904042080C185592680 @default.
- W2904042080 hasConceptScore W2904042080C192562407 @default.
- W2904042080 hasConceptScore W2904042080C512968161 @default.
- W2904042080 hasConceptScore W2904042080C515602321 @default.
- W2904042080 hasConceptScore W2904042080C540031477 @default.
- W2904042080 hasFunder F4320319952 @default.
- W2904042080 hasFunder F4320334593 @default.
- W2904042080 hasIssue "4" @default.
- W2904042080 hasLocation W29040420801 @default.
- W2904042080 hasOpenAccess W2904042080 @default.
- W2904042080 hasPrimaryLocation W29040420801 @default.
- W2904042080 hasRelatedWork W1454385451 @default.
- W2904042080 hasRelatedWork W1975143410 @default.
- W2904042080 hasRelatedWork W2062198518 @default.
- W2904042080 hasRelatedWork W2071785955 @default.
- W2904042080 hasRelatedWork W2607407904 @default.
- W2904042080 hasRelatedWork W3149206805 @default.
- W2904042080 hasRelatedWork W4200544918 @default.
- W2904042080 hasRelatedWork W4220714361 @default.
- W2904042080 hasRelatedWork W47700064 @default.
- W2904042080 hasRelatedWork W60976972 @default.
- W2904042080 hasVolume "11" @default.
- W2904042080 isParatext "false" @default.
- W2904042080 isRetracted "false" @default.
- W2904042080 magId "2904042080" @default.
- W2904042080 workType "article" @default.