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- W2904054237 abstract "A Diels–Alder strategy is reported to synthesize the complete set of hydroporphyrins: chlorins, bacteriochlorins, isobacteriochlorins, and pyrrocorphins. Porphyrins and Ni-porphyrins react with isobenzofuran in very high yields at 70 °C to form the corresponding chlorins. Electron-deficient porphyrins react with a second equivalent of isobenzofuran yielding exclusively bacteriochlorin (82%), and Ni-porphyrin gives only isobacteriochlorin (99%). All cycloadditions are completely regio- and stereoselective. The regiochemistry is correctly predicted using the ACID method." @default.
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- W2904054237 date "2018-12-11" @default.
- W2904054237 modified "2023-10-16" @default.
- W2904054237 title "One-Pot Approach to Chlorins, Isobacteriochlorins, Bacteriochlorins, and Pyrrocorphins" @default.
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- W2904054237 doi "https://doi.org/10.1021/acs.orglett.8b03433" @default.
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