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- W2904059020 abstract "Rh3+ ions are first impregnated on Group 4 metal oxides (TiO2, ZrO2, HfO2) in aqueous solution and, then reduced with aqueous solution of NaBH4 to form rhodium(0) nanoparticles (NPs) on the oxide surface. The analyses reveal that Rh(0) NPs are highly dispersed on the surface of TiO2, ZrO2, HfO2. Rh0/MO2 (M: Ti, Zr, Hf) NPs have high activity and reusability in releasing H2 from the hydrolysis of ammonia borane with an initial turnover frequency of 643, 198, and 188 min−1, respectively, at 25.0 ± 0.1 °C. The reusability of Rh0/ZrO2 and Rh0/HfO2 catalysts is higher than that of the Rh0/TiO2 catalyst." @default.
- W2904059020 created "2018-12-22" @default.
- W2904059020 creator A5020532334 @default.
- W2904059020 creator A5039448841 @default.
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- W2904059020 date "2019-05-01" @default.
- W2904059020 modified "2023-09-27" @default.
- W2904059020 title "Group 4 oxides supported Rhodium(0) catalysts in hydrolytic dehydrogenation of ammonia borane" @default.
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- W2904059020 doi "https://doi.org/10.1016/j.ijhydene.2018.11.162" @default.
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