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- W2904059575 abstract "The first enantioselective Michael addition of 2-acetyl azaarenes to β-CF3-β-(3-indolyl)nitroalkenes has been successfully achieved in the presence of a Co(II)/(imidazoline-oxazoline) complex as the catalyst. The reaction affords a series of CF3- and 3-indole-containing adducts featuring a trifluoromethylated all-carbon quaternary stereocenter in good to excellent yields (up to 99%) and enantioselectivities (up to 96% ee). Furthermore, the functional groups in the adducts including C═O, NO2, and the azaarene provide a large variety of useful transformations, leading to the formation of valuable intermediates such as optically active secondary alcohol, pyrroline, ester, and pyrrolidinone which all contain a 3-substituted indole and a trifluoromethylated all-carbon quaternary stereocenter." @default.
- W2904059575 created "2018-12-22" @default.
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- W2904059575 date "2018-12-13" @default.
- W2904059575 modified "2023-10-16" @default.
- W2904059575 title "Asymmetric Michael Addition of 2-Acetyl Azaarenes to β-CF<sub>3</sub>-β-(3-indolyl)nitroalkenes Catalyzed by a Cobalt(II)/(imidazoline-oxazoline) Complex" @default.
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- W2904059575 doi "https://doi.org/10.1021/acs.joc.8b02601" @default.
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