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- W2904112436 endingPage "8076" @default.
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- W2904112436 abstract "A geminal difluorination of alkenes based on I(I)/I(III) catalysis is disclosed, which is compatible with a range of electronically and substitutionally diverse styrenes (27 examples, up to 89% yield). Employing inexpensive p-TolI as the organocatalyst, turnover is enabled by Selectfluor-mediated oxidation to generate the ArIF2 species in situ. Extension to include α-substituted styrenes bearing fluorine-containing groups is disclosed and provides an expansive platform for the generation of fluorine-rich architectures." @default.
- W2904112436 created "2018-12-22" @default.
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- W2904112436 date "2018-12-11" @default.
- W2904112436 modified "2023-10-15" @default.
- W2904112436 title "Catalytic <i>Geminal</i> Difluorination of Styrenes for the Construction of Fluorine-rich Bioisosteres" @default.
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- W2904112436 doi "https://doi.org/10.1021/acs.orglett.8b03794" @default.
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