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- W2904138819 endingPage "1207" @default.
- W2904138819 startingPage "1172" @default.
- W2904138819 abstract "This review is focused on the recent developments in transition-metal-free transformations using N-tosylhydrazones, emerging building blocks in contemporary organic chemistry. Emphasis is given to their synthetic potential, scope, mechanism and limitations. N-Tosylhydrazones, derivatives of carbonyl compounds, can undergo a wide range of reactions under transition-metal-free reaction conditions. The chemical behaviour of tosylhydrazones is unique under different reaction conditions as they can act as diazo precursors, carbene sources, 1,3-dipoles, ambiphilic reagents, one-carbon synthons, and an alternative to the parent carbonyl compounds. These diverse reactivities have resulted in the development of novel C−C and C−heteroatom bond-forming reactions. The potential of N-tosylhydrazones in transition-metal-free reactions is evident from the synthesis of a handful of molecules such as cyclopropanes, di- and triarylmethanes, pyrazoles, triazoles, pyridazines, ethers, carbamates, thioacetals, thiadiazoles and many others." @default.
- W2904138819 created "2018-12-22" @default.
- W2904138819 creator A5035036837 @default.
- W2904138819 creator A5060943426 @default.
- W2904138819 creator A5079547566 @default.
- W2904138819 date "2018-12-14" @default.
- W2904138819 modified "2023-09-29" @default.
- W2904138819 title "Luxury of <i>N</i> ‐Tosylhydrazones in Transition‐Metal‐Free Transformations" @default.
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