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- W2904143213 abstract "In this chapter, we discuss advances in the formulation of multiphase systems, mainly emulsions containing cellulose nanomaterials as main stabilizer or costabilizer. From such systems, we demonstrate a number of developments toward materials with functional properties. The use of cellulose derivatives and microcrystalline cellulose has been reported extensively in the context of emulsions for food, pharma, and several other fields. In fact, the first studies on emulsification with cellulose involved microfibrillar cellulose. Despite the nonobvious differentiation between microfibrillar and nanofibrillar cellulose, activities with the latter types have been reported less frequently and only very recently. Here, we refer explicitly to plant-based nanocelluloses, mainly cellulose nanocrystals (CNC) and cellulose nanofibrils (CNF) as well as those from microorganisms (synthesized, e.g. by bacteria): BC fibrils (BC) and BC-derived CNC (bacterial cellulose nanocrystals – BCN). Indeed, reported work related to emulsions from these nanocelluloses spans only the last few years since this writing. This is a timely topic closely related to the principles of colloid and interface science. The application of CNC, CNF, BC, and BCN to stabilize interfaces originates from appealing properties that include shape factors, amphiphilicity (case of CNC and BCN), and their natural ability to assemble in networks and liquid crystals. Assemblies at the liquid–liquid interfaces will be highlighted for their viscosifying effects and as precursors of particle-stabilized emulsions (Pickering emulsions) that alone or in the presence of surfactants and polymers endow the multiphase system with excellent stability. A major driver for consideration of nanocellulose in emulsion stabilization includes their low toxicity and biocompatibility. Remarkably, nanocellulose-containing emulsions, especially BC, can be quite insensitive to changes in ionic strength, pH, and temperature, contrary to conventional emulsifiers such as thickening agents and surfactants. Many potential prospects exist for emulsified systems, such as the synthesis of a wide range of materials, from solid foams to stimuli-responsive constructs. Some of these possibilities will be highlighted in this contribution." @default.
- W2904143213 created "2018-12-22" @default.
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- W2904143213 date "2018-11-29" @default.
- W2904143213 modified "2023-10-16" @default.
- W2904143213 title "Nanocelluloses at the Oil-Water Interface: Emulsions Toward Function and Material Development" @default.
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- W2904143213 doi "https://doi.org/10.1002/9781119217619.ch16" @default.
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