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• W2904177174 abstract "We report the synthesis of α-trifluoromethyl benzylic amines through the vicinal fluoroarylation of gem-difluoro-2-azadienes. Our studies indicate that XPhos plays an important role as a phase transfer catalyst that promotes the addition of AgF to the difluoroazadiene, generating an α-trifluoromethyl azaallyl-silver intermediate that we have characterized by NMR spectroscopy. This intermediate likely transmetallates to Pd, coupling several aryl iodides to deliver products in up to 90% yield. Modification of the azadiene's activating group facilitates challenging cross-couplings." @default.
• W2904177174 created "2018-12-22" @default.
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• W2904177174 date "2018-12-06" @default.
• W2904177174 modified "2023-10-03" @default.
• W2904177174 title "Palladium-Catalyzed Synthesis of α-Trifluoromethyl Benzylic Amines via Fluoroarylation of <i>gem</i>-Difluoro-2-azadienes Enabled by Phosphine-Catalyzed Formation of an Azaallyl–Silver Intermediate" @default.
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• W2904177174 doi "https://doi.org/10.1021/acscatal.8b03999" @default.
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