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- W2904242258 abstract "Abstract A new diversified, rapid and easily accessible, N ‐heterocyclic carbene based palladacycle, SingaCycle TM ‐A1 exploited for the cross coupling reactions on heterocyclic amines. This Pd‐NHC catalyst is considered to be merely stable and takes part in dynamic conversion of various organic functionalities. Herein, we report its first time use in the synthesis of C‐ and N ‐ diaryl/ heteroaryl pyridine analogues from the less active parent 5‐bromopyridine‐2‐amine via sequential Suzuki‐Miyaura and Buchwald couplings. Surprisingly, both the coupling reactions proceed very smoothly and efficiently under mild reaction conditions in green solvent system (ethanol:water) at a faster rate. Moreover 1 mol% of the catalyst is sufficient to proceed the reactions and obtain comparatively better results." @default.
- W2904242258 created "2018-12-22" @default.
- W2904242258 creator A5005849423 @default.
- W2904242258 creator A5008835680 @default.
- W2904242258 creator A5068531485 @default.
- W2904242258 date "2018-12-11" @default.
- W2904242258 modified "2023-09-26" @default.
- W2904242258 title "SingaCycle<sup>TM</sup>‐A1‐Catalyzed Successive Suzuki‐Miyaura and Buchwald Couplings for the Synthesis of Various New Pyridine Analogues" @default.
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- W2904242258 doi "https://doi.org/10.1002/slct.201802282" @default.
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