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• W2904255029 endingPage "1147" @default.
• W2904255029 startingPage "1143" @default.
• W2904255029 abstract "Abstract The structural orientation of an amphiphilic crystalline polymer to a highly ordered microphase‐separated lamellar structure on a hydrophobic surface is presented. It is formed by the surface graft polymerization of poly(ethylene glycol)behenyl ether methacrylate onto poly(trimethylsilyl) propyne in the presence of allylamine. In particular, allylamine plays a pivotal role in controlling the crystalline phase, configuration, and permeation properties. The resulting materials are effectively used to improve the CO 2 capture property of membranes. Upon the optimization of the reaction conditions, a high CO 2 permeability of 501 Barrer and a CO 2 /N 2 ideal selectivity of 77.2 are obtained, which exceed the Robeson upper bound limit. It is inspiring to surpass the upper bound limit via a simple surface modification method." @default.
• W2904255029 created "2018-12-22" @default.
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• W2904255029 date "2018-12-21" @default.
• W2904255029 modified "2023-10-15" @default.
• W2904255029 title "Orientation of an Amphiphilic Copolymer to a Lamellar Structure on a Hydrophobic Surface and Implications for CO ₂ Capture Membranes" @default.
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• W2904255029 doi "https://doi.org/10.1002/anie.201811450" @default.
• W2904255029 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30520206" @default.
• W2904255029 hasPublicationYear "2018" @default.
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