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- W2904317002 abstract "A novel near-infrared fluorescent probe RHCC was devised and synthesized. It exhibits high specificity to Fe3+ compared to other metals in aqueous solutions. The detection limit of RHCC was 1.2 × 10−7 M and the complexation stability constant was 5.807 × 104 M−1. The binding ratio of RHCC and Fe3+ was 1:1 which was measured through MS, FTIR and Job's plot. The energy gap between HOMO and LUMO of RHCC was 3.22 eV, while RHCC-Fe3+ complex was 0.95 eV. This result means the binding of probe RHCC and Fe3+ lowers the RHCC-Fe3+ complex's energy gap and makes it more stable. What's more, in living cells and zebrafishes studies, probe RHCC was no significant cytotoxic effect, indicating it could monitor Fe3+ in biological system." @default.
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- W2904317002 date "2019-03-01" @default.
- W2904317002 modified "2023-09-26" @default.
- W2904317002 title "A novel near-infrared “turn-on” fluorescent probe for selective detection of Fe3+ and its application in vitro imaging" @default.
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- W2904317002 doi "https://doi.org/10.1016/j.jlumin.2018.12.014" @default.
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