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- W2904342203 abstract "From potentiodynamic and potentiostatic electrochemical methods it was assessed, for the first time, the kinetics and mechanism involved during the electrochemical synthesis of palladium nanoparticles, PdNPs, from a deep eutectic solvent, DES, formed by the choline chloride and ethylene glycol eutectic mixture at 298 K. It was found that the potentiostatically electrodeposited PdNPs were formed through multiple 3D nucleation with diffusion-controlled growth. The nucleation frequency and the nucleation active sites increased linearly and exponentially with applied potential, respectively, and the Pd(II) ions diffusion coefficient, D, in DES was D = (2.77 ± 0.19) 10−7 cm2s−1. The morphology and composition of the PdNPs were characterized by SEM and XPS, respectively. The PdNPs were homogeneously dispersed onto the GCE surface, with monodispersed size ((41 ± 5) nm) and were formed mainly by metallic palladium with small amounts of PdO and PdO2. Furthermore, it was also shown that the GCE-PdNPs modified electrode depicts a high catalytic activity toward formic acid electrochemical oxidation reaction, revealing a mass activity of (4200 ± 100) mA mgPd−1 at the peak potential, much greater than those reported so far for other PdNPs synthesized by means of sophisticated, time-consuming methods." @default.
- W2904342203 created "2018-12-22" @default.
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- W2904342203 date "2018-12-06" @default.
- W2904342203 modified "2023-10-18" @default.
- W2904342203 title "Palladium Nanoparticles Electrodeposition onto Glassy Carbon from a Deep Eutectic Solvent at 298 K and Their Catalytic Performance toward Formic Acid Oxidation" @default.
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- W2904342203 doi "https://doi.org/10.1149/2.0251901jes" @default.
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