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- W2904348577 abstract "The synthesis of aliphatic polyesters by the ring-opening polymerization of cyclic monoesters was discovered by Carothers in the 1930s. Since then, a plethora of catalysts and initiators have been discovered to promote this polymerization. Nowadays, steadily increasing attention is paid to organocatalysts and, among them, acids, bases, and H-bond donors and acceptors. Organocatalysts today available for the polymerization of medium size cyclic monoesters such as δ-valerolactone and ε-caprolactone will be reviewed. Special attention will be paid to dual catalysts capable of activating both the initiator and the monomer. The most efficient catalysts promote fast and selective ring-opening polymerization. The mechanism based either on ionic interactions, the establishment of H-bonds or nucleophilic activation will be discussed. The importance of ring size will be highlighted by the organocatalyzed polymerization of β-butyrolactone, γ-butyrolactone and pentadecalactone as a typical macrocyclic monoester." @default.
- W2904348577 created "2018-12-22" @default.
- W2904348577 creator A5068217923 @default.
- W2904348577 creator A5072726180 @default.
- W2904348577 date "2018-11-20" @default.
- W2904348577 modified "2023-10-14" @default.
- W2904348577 title "Ring-opening Polymerization of Lactones" @default.
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- W2904348577 doi "https://doi.org/10.1039/9781788015738-00198" @default.
- W2904348577 hasPublicationYear "2018" @default.
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