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• W2904353750 abstract "Two practical entries to arylomycin antibiotics core structures are investigated. In route A, the activation of l-Hpg for the key macrolactamization step is achieved in 89% yield in the presence of unprotected phenol and amine functionalities. Alternatively, a propanephosphonic acid anhydride (T3P)-promoted coupling between thel-Tyr and l-Ala moieties in route B led to a facile macrolactamization in 68% yield with a marked reduction in competing oligomerization." @default.
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• W2904353750 date "2018-12-19" @default.
• W2904353750 modified "2023-10-07" @default.
• W2904353750 title "Macrolactamization Approaches to Arylomycin Antibiotics Core" @default.
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• W2904353750 doi "https://doi.org/10.1021/acs.orglett.8b03603" @default.
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