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• W2904376036 abstract "There is a growing interest in epitaxial interfaces between nonisostructural transition-metal oxides that might exhibit interfacial correlated-electron effects. In this study, we show at the atomic scale that a fully coherent and very stable interface between rutile-type TiO2 and corundum-type Ti2O3, namely (100)TiO2//(1120)Ti2O3, is formed through a topotactic transition. A two-dimensional electron gas is generated at the interface through electron transfer from Ti2O3 to TiO2. In addition, the existence of Ti interstitials close to the interface indicates that the topotactic transition occurs via the migration of cations, instead of oxygen as suggested previously. Employing the topotaxy between oxides of different crystal structures offers rich choices to construct coherent interfaces." @default.
• W2904376036 created "2018-12-22" @default.
• W2904376036 creator A5051498051 @default.
• W2904376036 creator A5055060386 @default.
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• W2904376036 date "2018-12-12" @default.
• W2904376036 modified "2023-10-16" @default.
• W2904376036 title "Coherent Topotactic Interface between Corundum and Rutile Structures" @default.
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• W2904376036 doi "https://doi.org/10.1021/acs.jpcc.8b09878" @default.
• W2904376036 hasPublicationYear "2018" @default.
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