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• W2904394057 abstract "Abstract In this work, a series of SO42−/TiO2/γ-Al2O3 solid acid catalysts were synthesized by impregnation method, in which nano-TiO2 was prepared by sol–gel method, and then the nano-TiO2 sol was loaded on porous γ-Al2O3 supporter through impregnation. The structure and property of catalyst were characterized by XRD, N2-BET, SEM, TEM, XPS, NH3-TPD, Pyridine-IR and FT-IR. In addition, the catalyst of chelate bidentate coordination acid center model was established. The catalytic performance test was carried out in the esterification of n-butyl alcohol with lauric acid and the catalyst showed excellent activity. The experimental results showed that the medium strength acid sites were more dominant active sites than the strong and weak acid sites for the rapid esterification reaction. Its kinetic behaviors and activation energy were studied for the esterification under the catalytic reaction condition." @default.
• W2904394057 created "2018-12-22" @default.
• W2904394057 creator A5028573018 @default.
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• W2904394057 date "2019-11-01" @default.
• W2904394057 modified "2023-09-24" @default.
• W2904394057 title "Preparation of solid acid catalyst SO42−/TiO2/γ-Al2O3 for esterification: A study on catalytic reaction mechanism and kinetics" @default.
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• W2904394057 doi "https://doi.org/10.1016/j.cjche.2018.11.021" @default.
• W2904394057 hasPublicationYear "2019" @default.
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