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- W2904397269 abstract "A sterically demanding derivative of a previously introduced chiral‐at‐metal ruthenium(II) catalyst scaffold is introduced. It is composed of two bidentate furo[3,2‐ b ]pyridyl functionalized N‐heterocyclic carbene ligands. Their cis ‐coordination generates helical chirality and a stereogenic ruthenium center. Two additional labile acetonitriles compose the catalytic site which is highly shielded by two 2‐( tert ‐butyl)furo[3,2‐ b ]pyridine moieties. The synthesis of the non‐racemic ruthenium catalyst and its catalytic properties for the enantioselective alkynylation of 2,2,2‐trifluoroacetophenone and pentafluorobenzaldehyde are reported and compared with sterically less demanding derivatives." @default.
- W2904397269 created "2018-12-22" @default.
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- W2904397269 date "2018-12-27" @default.
- W2904397269 modified "2023-09-26" @default.
- W2904397269 title "Chiral‐at‐Ruthenium Catalyst with Sterically Demanding Furo[3,2‐ <i>b</i> ]pyridine Ligands" @default.
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- W2904397269 doi "https://doi.org/10.1002/ejic.201801362" @default.
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