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- W2904408648 abstract "Today, many chemical modifications are being made to increase the utilization of chitosan and to make the best use of it. In this study, four novel cross-linked chitosan derivatives in the form of hydrogel (CS-L1 CS-L2, CS-L3, and CS-L4) were prepared by the condensation of chitosan with anisole-based phenolic and nonphenolic aromatic dicarbonyls. Structural analyses were performed by elemental analysis (C, H, N), scanning electron microscopy, Fourier transform infrared, 13C-CP/MAS (cross-polarization, magic angle spinning) nuclear magnetic resonance, powder X-ray diffraction, and thermogravimetric analysis techniques. Metal ion uptake capacities were studied for selected transition-metal cations in aqueous medium. The amount of metal ions was determined by microwave plasma-atomic emission spectroscopy. In addition, the swelling behaviors were investigated at different temperatures (25 and 37 °C) and at different pH values (3, 7, and 10). The order of the selectivity of cross-linked chitosan derivatives toward metal ions was found to be Cu(II) > Cd(II) > Fe(II) > Co(II) > Ni(II). The results showed that the derivatives exhibited the property of hydrogel and suggest that they could be applied in many areas such as metal removing, water removing, and biological applications." @default.
- W2904408648 created "2018-12-22" @default.
- W2904408648 creator A5078295902 @default.
- W2904408648 creator A5081126073 @default.
- W2904408648 date "2018-12-17" @default.
- W2904408648 modified "2023-10-18" @default.
- W2904408648 title "Synthesis, Characterization, Swelling, and Metal Uptake Studies of Aryl Cross-Linked Chitosan Hydrogels" @default.
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- W2904408648 doi "https://doi.org/10.1021/acsomega.8b01872" @default.
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