FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2904440306> ?p ?o ?g. }

• W2904440306 endingPage "122" @default.
• W2904440306 startingPage "122" @default.
• W2904440306 abstract "From a security point of view, detecting and quantifying explosives in mixed environments is required to identify potentially concealed explosives. Electrochemistry offers a viable method to detect nitroaromatic explosive compounds owing to the presence of easily reducible nitro groups that give rise to a current signal. However, their reduction potentials can overlap with interfering species, making it difficult to distinguish particular compounds. We have therefore examined the effect of oxygen, moisture, and other nitroaromatic species on the cyclic voltammetry and square wave voltammetry of nitroaromatic compounds of a range of mixed environments, focussing on 2,4,6-trinitrotoluene (TNT) and 2,4-dinitrotoluene (DNT) as model analytes, and using the hydrophobic room-temperature ionic liquid (RTIL) [P14,6,6,6][NTf2] as the solvent. Oxygen (0–20% vol.) minimally affected the current of the first reduction peak of TNT in [P14,6,6,6][NTf2], but significantly affects the current for DNT. The impact of water (0 to 86% relative humidity), however, was much more dramatic – even in the hydrophobic RTIL, water significantly affected the currents of the analyte peaks for TNT and DNT, and gave rise to additional reduction features, further contributing to the current. Additionally, the voltammetry of other related di- and tri-nitro compounds (2,6-dinitrotoluene, 1,3-dinitrobenzene, 2,4,6-trinitrotoluene, 1,3,5-trinitrobenzene, and musk xylene) was also studied to understand how different substituents on the aromatic ring may affect the reduction potentials. A 50:50 mixture of TNT and DNT revealed that both analytes could be separately identified and quantified using square wave voltammetry. Overall, this information is useful in determining the effect of other species on the current signals of electrochemical explosive sensors, and reveals that it may be necessary to dry the aprotic RTIL electrolyte when used in humid environments." @default.
• W2904440306 created "2018-12-22" @default.
• W2904440306 creator A5027601300 @default.
• W2904440306 creator A5042326649 @default.
• W2904440306 date "2019-01-01" @default.
• W2904440306 modified "2023-10-16" @default.
• W2904440306 title "Electrochemical Detection of Explosive Compounds in an Ionic Liquid in Mixed Environments: Influence of Oxygen, Moisture, and Other Nitroaromatics on the Sensing Response" @default.
• W2904440306 cites W1649400226 @default.
• W2904440306 cites W1964492496 @default.
• W2904440306 cites W1974842171 @default.
• W2904440306 cites W1982479518 @default.
• W2904440306 cites W1990279333 @default.
• W2904440306 cites W2001081232 @default.
• W2904440306 cites W2002751214 @default.
• W2904440306 cites W2007865521 @default.
• W2904440306 cites W2008110587 @default.
• W2904440306 cites W2018607689 @default.
• W2904440306 cites W2019934632 @default.
• W2904440306 cites W2027132257 @default.
• W2904440306 cites W2033654208 @default.
• W2904440306 cites W2036842226 @default.
• W2904440306 cites W2038956444 @default.
• W2904440306 cites W2043788911 @default.
• W2904440306 cites W2045186948 @default.
• W2904440306 cites W2046912225 @default.
• W2904440306 cites W2048607901 @default.
• W2904440306 cites W2058260338 @default.
• W2904440306 cites W2066273566 @default.
• W2904440306 cites W2075470483 @default.
• W2904440306 cites W2075565110 @default.
• W2904440306 cites W2076618318 @default.
• W2904440306 cites W2079726351 @default.
• W2904440306 cites W2081243834 @default.
• W2904440306 cites W2086713708 @default.
• W2904440306 cites W2088974888 @default.
• W2904440306 cites W2102522658 @default.
• W2904440306 cites W2117103350 @default.
• W2904440306 cites W2122250145 @default.
• W2904440306 cites W2126454251 @default.
• W2904440306 cites W2127874529 @default.
• W2904440306 cites W2135748525 @default.
• W2904440306 cites W2141713267 @default.
• W2904440306 cites W2167709106 @default.
• W2904440306 cites W2286748995 @default.
• W2904440306 cites W2313690419 @default.
• W2904440306 cites W2318767114 @default.
• W2904440306 cites W2329334245 @default.
• W2904440306 cites W2345677140 @default.
• W2904440306 cites W2507967442 @default.
• W2904440306 cites W2518926114 @default.
• W2904440306 cites W2597828400 @default.
• W2904440306 cites W2765944356 @default.
• W2904440306 cites W2883225122 @default.
• W2904440306 cites W2890845638 @default.
• W2904440306 cites W3023319571 @default.
• W2904440306 cites W4248104288 @default.
• W2904440306 doi "https://doi.org/10.1071/ch18396" @default.
• W2904440306 hasPublicationYear "2019" @default.
• W2904440306 type Work @default.
• W2904440306 sameAs 2904440306 @default.
• W2904440306 citedByCount "8" @default.
• W2904440306 countsByYear W29044403062019 @default.
• W2904440306 countsByYear W29044403062020 @default.
• W2904440306 countsByYear W29044403062021 @default.
• W2904440306 countsByYear W29044403062022 @default.
• W2904440306 countsByYear W29044403062023 @default.
• W2904440306 crossrefType "journal-article" @default.
• W2904440306 hasAuthorship W2904440306A5027601300 @default.
• W2904440306 hasAuthorship W2904440306A5042326649 @default.
• W2904440306 hasBestOaLocation W29044403062 @default.
• W2904440306 hasConcept C10390740 @default.
• W2904440306 hasConcept C147789679 @default.
• W2904440306 hasConcept C148093993 @default.
• W2904440306 hasConcept C154238967 @default.
• W2904440306 hasConcept C154881586 @default.
• W2904440306 hasConcept C161790260 @default.
• W2904440306 hasConcept C17525397 @default.
• W2904440306 hasConcept C178790620 @default.
• W2904440306 hasConcept C179104552 @default.
• W2904440306 hasConcept C185592680 @default.
• W2904440306 hasConcept C2775856698 @default.
• W2904440306 hasConcept C2777869211 @default.
• W2904440306 hasConcept C2779525745 @default.
• W2904440306 hasConcept C2779603750 @default.
• W2904440306 hasConcept C2780263894 @default.
• W2904440306 hasConcept C2780471494 @default.
• W2904440306 hasConcept C2780554229 @default.
• W2904440306 hasConcept C2780639532 @default.
• W2904440306 hasConcept C2910635913 @default.
• W2904440306 hasConcept C43617362 @default.
• W2904440306 hasConcept C52859227 @default.
• W2904440306 hasConcept C540031477 @default.
• W2904440306 hasConceptScore W2904440306C10390740 @default.
• W2904440306 hasConceptScore W2904440306C147789679 @default.
• W2904440306 hasConceptScore W2904440306C148093993 @default.
• W2904440306 hasConceptScore W2904440306C154238967 @default.
• W2904440306 hasConceptScore W2904440306C154881586 @default.
• W2904440306 hasConceptScore W2904440306C161790260 @default.

• next