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• W2904481266 abstract "tert-Butylphosphonic acid and rare-earth precursors are employed to construct four trinuclear rare-earth phosphonate clusters, RE3(tBuPO3)2(hfac)5(CH3OH)8]·2CH3OH (RE = Eu, Y, Pr, and Sm; hfac = hexafluoroacetylacetonate), which are composed of three RE3+ ions alternately bridged by two phosphonates. With the introduction of bismuth oxido diketonate, [Bi9O7(hfac)13], three different types of rare-earth/bismuth phosphonate clusters, Bi12RE2 (RE = Pr and Sm), Bi6Eu7, and Bi6Y9, are successfully obtained via variation of the reaction conditions, and they are the first reported examples of bismuth–oxo clusters encapsulated by cyclic rare-earth–oxo or rare-earth/bismuth–oxo phosphonate clusters, respectively. These clusters show obvious absorption in the UV region, and the Eu-containing clusters exhibit bright-red fluorescence." @default.
• W2904481266 created "2018-12-22" @default.
• W2904481266 creator A5023571225 @default.
• W2904481266 creator A5078853797 @default.
• W2904481266 creator A5086288228 @default.
• W2904481266 date "2018-12-07" @default.
• W2904481266 modified "2023-10-16" @default.
• W2904481266 title "Hybrid Rare-Earth(III)/Bismuth(III) Clusters Assembled with Phosphonates" @default.
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• W2904481266 doi "https://doi.org/10.1021/acs.inorgchem.8b02811" @default.
• W2904481266 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30525540" @default.
• W2904481266 hasPublicationYear "2018" @default.
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