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- W2904647536 abstract "A most simple way to reduce the rate of polymer combustion by enhancing the effectiveness of fire retardants is described in this paper. The discussion is focused on a simplified kinetic model of the overall cyclic chemical process that controls the polymer combustion. This latter consists of two connected chemical reactions mutually feeding each other: the condensed phase polymer pyrolysis and the gas phase oxidation of the issued volatiles. It is shown that the chemical kinetics of this “Fire Loop” results in a more than additive (“synergistic”) effect of different fire retardants if they act by reducing both the rate of polymer pyrolysis and of volatiles oxidation as compared to combining fire retardants acting in the same phase. Furthermore, the way to maximise this inherent synergistic effect, based on the respective effectiveness of the combined fire retardants, is discussed." @default.
- W2904647536 created "2018-12-22" @default.
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- W2904647536 date "2019-02-01" @default.
- W2904647536 modified "2023-10-16" @default.
- W2904647536 title "The chemical kinetics of the polymer combustion allows for inherent fire retardant synergism" @default.
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- W2904647536 doi "https://doi.org/10.1016/j.polymdegradstab.2018.12.018" @default.
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