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- W2904686540 abstract "通过核磁共振（NMR）技术研究了阳离子表面活性剂，包括单链（DTAC）和双链（C12-C4-C12和C12-C8-C12）氯化物季铵盐，与非离子表面活性剂壬基酚聚氧乙烯醚（NP-10）组成的3种复配体系的相互作用及作用点、排列方式、混合胶束中分子间与分子内作用的变化规律等.2D NOESY技术证明了这3种复配体系相互作用力大小顺序为NP-10/C12-C8-C12 > NP-10/C12-C4-C12 > NP-10/DTAC，它们的相互作用点相同但作用点数目不同.自扩散系数显示NP-10对混合胶束的动力学半径影响大于季铵盐.弛豫时间表明，当NP-10/DTAC和NP-10/C12-Cs-C12（s=4或8）的混合摩尔比分别为1：3和1：2时，复配体系中分子间的相互作用力开始减小，分子内作用开始起主导作用，这暗示它们最佳摩尔配比分别为1：3和1：2，空间距离也佐证了这一结论." @default.
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- W2904686540 date "2017-03-05" @default.
- W2904686540 modified "2023-09-24" @default.
- W2904686540 title "NP-10与单链、双链季铵盐三种复配体系相互作用规律的NMR研究" @default.
- W2904686540 doi "https://doi.org/10.11938/cjmr20170103" @default.
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