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• W2904687596 endingPage "382" @default.
• W2904687596 startingPage "359" @default.
• W2904687596 abstract "Abstract Reservoirs that host CO 2 ‐H 2 S‐bearing gases provide a key insight into crustal redox reactions such as thermochemical sulfate reduction (TSR). Despite this, there remains a poor understanding of the extent, duration, and the factors limiting this process on a reservoir scale. Here we show how a combination of petrography, fluid inclusion, rare earth element (REE), and carbon (δ 13 C), oxygen (δ 18 O), and sulfur (δ 34 S) stable isotope data can disentangle the fluid history of the world's largest CO 2 accumulation, the LaBarge Field in Wyoming, USA. The carbonate‐hosted LaBarge Field was charged with oil around 80 Ma ago, which together with nodular anhydrite represent the reactants for TSR. The nodules exhibit two distinct trends of evolution in δ 13 C with both δ 34 S and δ 18 O that may be coupled to two different processes. The first trend was interpreted to reflect the coupled dissolution of anhydrite and reduction to elemental sulfur and the oxidation of organic compounds and associated precipitation of calcite during TSR. In contrast, the second trend was interpreted to be the result of the hydrothermal CO 2 influx after the cessation of TSR. In addition, mass balance calculations were performed to estimate an approximate TSR reaction duration of 80 ka and to identify the availability of organic compounds as the limiting factor of the TSR process. Such an approach provides a tool for the prediction of TSR occurrence elsewhere and advancing our understanding of crustal fluid interactions." @default.
• W2904687596 created "2018-12-22" @default.
• W2904687596 creator A5002246119 @default.
• W2904687596 creator A5010858767 @default.
• W2904687596 creator A5036557426 @default.
• W2904687596 creator A5058656041 @default.
• W2904687596 creator A5070024085 @default.
• W2904687596 creator A5078355178 @default.
• W2904687596 creator A5086042756 @default.
• W2904687596 date "2019-01-01" @default.
• W2904687596 modified "2023-10-06" @default.
• W2904687596 title "Constraining the Fluid History of a CO ₂ ‐H ₂ S Reservoir: Insights From Stable Isotopes, REE, and Fluid Inclusion Microthermometry" @default.
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