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• W2904697194 abstract "Methods for the radiolabeling of biologics with fluorine-18 have been of interest for several decades. A common approach consists in the preparation of a prosthetic reagent, a small molecule bearing a fluorine-18 that is conjugated with the macromolecule to an appropriate function. Click chemistry, and more particularly cycloadditions, is an interesting approach to radiolabel molecules thanks to mild reaction conditions, high yields, low by-products formation, and strong orthogonality. Moreover, the chemical functions involved in the cycloaddition reaction are stable in the drastic radiofluorination conditions, thus allowing a simple radiosynthetic route to prepare the prosthetic reagent. We report herein the radiosynthesis of 18 F-FPyZIDE, a pyridine-based azide-bearing prosthetic reagent. We exemplified its conjugation via copper-catalyzed cycloaddition (CuAAC) and strain-promoted cycloaddition (SPAAC) with several terminal alkyne or strained alkyne model compounds." @default.
• W2904697194 created "2018-12-22" @default.
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• W2904697194 date "2019-01-02" @default.
• W2904697194 modified "2023-09-25" @default.
• W2904697194 title "[¹⁸F]FPyZIDE: A versatile prosthetic reagent for the fluorine-18 radiolabeling of biologics via copper-catalyzed or strain-promoted alkyne-azide cycloadditions" @default.
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• W2904697194 doi "https://doi.org/10.1002/jlcr.3701" @default.
• W2904697194 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30556584" @default.
• W2904697194 hasPublicationYear "2019" @default.
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