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• W2904804936 startingPage "7942" @default.
• W2904804936 abstract "The serendipitous addition of a phenolate to FeCl3/TMEDA/Ti(OEt)4 enables a strong Fe/Ti cooperativity that can efficiently catalyze a general and selective biaryl-coupling reaction. In the absence of phosphine or NHC ligands, various aryl chlorides, bromides, and iodides can couple with a variety of common and Knochel-type aryl Grignard reagents. A wide range of sensitive functional groups in either coupling partner can be tolerated. This bimetallic cocatalysis not only remarkably extends the scope of Fe-catalyzed biaryl couplings but also provides a solution to the problem of functional group compatibility of Grignard reagents." @default.
• W2904804936 created "2018-12-22" @default.
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• W2904804936 date "2018-12-07" @default.
• W2904804936 modified "2023-10-15" @default.
• W2904804936 title "Phenolate Enabled General and Selective Fe/Ti Cocatalyzed Biaryl Cross-Couplings between Aryl Halides and Aryl Grignard Reagents" @default.
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• W2904804936 doi "https://doi.org/10.1021/acs.orglett.8b03513" @default.
• W2904804936 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30525681" @default.
• W2904804936 hasPublicationYear "2018" @default.
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